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Application of inhibitors for anti-corrosion protection of forest machines

https://doi.org/10.21266/2079-4304.2022.240.264-276

Abstract

Modern forestry machines are operated in various climatic conditions, characterized by sudden temperature changes, high humidity, and dustiness. The impact on the paint coatings of an aggressive environment leads to their destruction and the occurrence of corrosion processes on the surface of the equipment. The purpose of this work was to improve the protective properties of paint coatings by introducing organic corrosion inhibitors into them. For testing, flat samples of sheet steel St.3 were used, 140x70 mm in size, 0.8 – 1.0 mm thick with a clean surface. The studied paintwork consisted of ML-152 enamel with inhibitors introduced into it. The following organic compounds were studied as inhibitors: 6-(paminobenzenesulfamido)- 2,4-dimethoxypyrimidine, p-aminobenzenesulfaguanidine, 2-(p-aminobenzenesulfamido)-thiazole, 2-(p-aminobenzenesulfamido)-4,6 dimethylpyrimidine, benzotriazole . Using visual and electrochemical methods, water extracts from a polymer coating with additives introduced into it, the corrosion resistance of steel samples with applied paint coatings with additives, and the electrical insulating properties of paint coating films were studied. As a result of the work carried out, it was shown that water extracts from a polymer coating based on ML-152 enamel, with additives introduced into it, have a corrosion-inhibiting effect. It has been established that the additives introduced into the ML-152 enamel increase the anodic polarization of the samples and slow down the electrode processes on the metal during the entire exposure time. The studied additives increase the resistance of polymer films up to 1.8 Ohm. The most effective additives that slow down corrosion when they are introduced into ML-152 enamel are 2-(p-aminobenzenesulfamido)-thiazole and 2-(paminobenzenesulfamido)- 4,6 dimethylpyrimidine.

About the Authors

E. G. Rakovskaya
St.Petersburg State Forest Technical University
Russian Federation

RAKOVSKAYA Ekaterina G. – PhD (Chemistry), Associate Professor

194021. Institute per. 5. St. Petersburg



N. G. Zanko
St.Petersburg State Forest Technical University
Russian Federation

ZANKO Natalya G. – PhD (Technical), Associate Professor

194021. Institute per. 5. St. Petersburg



References

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3. Rakovskaya E.G., Kudryashova O.A. The use of a modified rust converter P-2 to protect forest machines from corrosion. News of the St. Petersburg Forestry Academy, 2017, iss. 221, pp. 309–323.

4. Rakovskaya E.G., Zanko N.G. Assessment of the possibility of using wastes from pulp and paper industry in mechanical engineering. IOP Conference Series: Earth and Environmental Science: 5, Policy, Industry, Science fnd Education, Saint Petersburg, 2020, p. 012068. DOI: 10.1088/1755-1315/574/1/012068. (In Russ.)

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6. Rosenfeld I.L., Protection of metals from corrosion by paint and varnish coatings. M.: Chemistry, 1987. 167 p. (In Russ.)


Review

For citations:


Rakovskaya E.G., Zanko N.G. Application of inhibitors for anti-corrosion protection of forest machines. Izvestia Sankt-Peterburgskoj lesotehniceskoj akademii. 2022;(240):264-276. (In Russ.) https://doi.org/10.21266/2079-4304.2022.240.264-276

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ISSN 2079-4304 (Print)
ISSN 2658-5871 (Online)