NMR analysis of pine tree oleoresin composition of the Pinus subgenus
https://doi.org/10.21266/2079-4304.2021.237.242-257
Abstract
The NMR method was used to analyze oleoresin composition of eight species of Pinus subgenus: Austrian black (P. nigra), Alleps (P. halepensis), mountain (P. montana), hard (P. rigida), Koch (P. kochiana Klotsch), Murray (P. murrayana Balf), common (P. sylvestris) and Pallas (P. nigra subsp. pallasiana) growing in different areas. In addition, the content of resin acids isolated in 1963 from the oleoresins of three species of pines belonging to the same subgenus: black Austrian, hooked (P. uncinata) and Kulunda (P. sylvestris ssp. Kulundensis) was studied. It was found that the oleoresin composition of the named pine species is well described by the presence of eight resin acids (abietic, dehydroabietic, isopimaric, levopimaric, neoabietic, palustrine, pimaric and sandaracopymaric) and nine monoterpenes (camphor, 3-caren, limonene, myrcene, α-pinene, β-pinene, terpinolen, β-felandreene, p-cymol). The quantitative content of these resin acids depends on many factors (pine species, time and place of oleoresin collection, and sample collection and storage conditions). In addition, isomerization and oxidation reactions are observed, leading to a redistribution of the composition. In the studied oleoresins, the content of monoterpenes differs greatly, being the lowest in Alleps pine and the highest in Scots pine.
About the Authors
E. D. Skakovskii
State scientific institution «Institute of physical organic chemistry national academy of sciences of Belarus»
Belarus
Belarus
SKAKOVSKII Evgeny D. – leading researcher in the laboratory of physicochemical methods of research
220072. Surganov str. 13. Minsk
L. Yu. Tychinskaya
State scientific institution «Institute of physical organic chemistry national academy of sciences of Belarus»
Belarus
Belarus
TYCHINSKAYA Lyudmila Yu. – head of the laboratory of physico-chemical methods of research
220072. Surganov str. 13. Minsk
A. I. Hapankova
State scientific institution «Institute of physical organic chemistry national academy of sciences of Belarus»
Belarus
Belarus
HAPANKOVA Alena I. – junior researcher of the Laboratory of Membrane Processes
220072. Surganov str. 13. Minsk
I. A. Latyshevich
State scientific institution «Institute of physical organic chemistry national academy of sciences of Belarus»
Belarus
Belarus
LATYSHEVICH Iryna A. – researcher of the Laboratory of Membrane Processes
220072. Surganov str. 13. Minsk
H. G. Shutava
State Scientific Institution «Central Botanical Garden of the National Academy of Sciences of Belarus»
Belarus
Belarus
SHUTAVA Hanna G. ‒ leading Researcher, Laboratory of Applied Biochemistry
220012. Surganov str. 2B. Minsk
S. N. Shysh
State Scientific Institution «Central Botanical Garden of the National Academy of Sciences of Belarus»
Belarus
Belarus
SHYSH Sviatlana N. ‒ Researcher, Laboratory of Applied Biochemistry
220012. Surganov str. 2B. Minsk
S. A. Lamotkin
Institution of education «Belarusian State Technological University»
Belarus
Belarus
LAMOTKIN Sergey A. – associate professor of the department of physicochemical methods of product certification
220006. Sverdlova str. 13a. Minsk
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Review
For citations:
Skakovskii E.D., Tychinskaya L.Yu., Hapankova A.I., Latyshevich I.A., Shutava H.G., Shysh S.N., Lamotkin S.A. NMR analysis of pine tree oleoresin composition of the Pinus subgenus. Izvestia Sankt-Peterburgskoj lesotehniceskoj akademii. 2021;(237):242-257. (In Russ.) https://doi.org/10.21266/2079-4304.2021.237.242-257
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