Preview

Izvestia Sankt-Peterburgskoj lesotehniceskoj akademii

Advanced search

nfluence of birch bark content in press raw materials on the properties of birch sawdust-based plastic without resins

https://doi.org/10.21266/2079-4304.2024.250.333-352

Abstract

Samples of plastic without resin (PWR) were produced using a wood filler with varying proportions of birch bark. The PWR samples were pressed in a sealed mold under a pressure of 40 MPa and at a temperature of 180 °C, followed by cooling without pressure release until reaching 40 °C. The resulting samples underwent testing for density, flexural strength, flexural modulus of elasticity, Brinell hardness, impact toughness, water absorption, and swelling after 24 hours. Additionally, biostability was assessed in soil for 90 days and in active soil for 105 days. Hydrophobicity was also evaluated based on the contact angle. Based on the test results, the optimal composition ratio for the press material was determined using birch sawdust with a 50% addition of birch bark. At this ratio, the material exhibited the following properties: density – 909 kg/m³, modulus of elasticity – 1566 MPa, flexural strength – 8.9MPa, Brinell hardness – 17 MPa, impact toughness – 3.818 kJ/m², water absorption in 24 hours – 32%, and swelling – 7%. A correlation was found between increased birch bark content in the press material and enhanced biostability, attributed to its high hydrophobicity and antiseptic properties.

About the Authors

A. V. Artyomov
Ural State Forest Engineering University
Russian Federation

Artyomov Artyom V. – PhD (Technical), Associate Professor of the department technology of pulp and paper industries and polymer processing 

620100. Siberian tract str. 37. Yekaterinburg



N. G. Vlasov
Ural State Forest Engineering University
Russian Federation

Vlasov Nicolay G. – master student of department technology of pulp and paper industries and polymer processing 

620100. Siberian tract str. 37. Yekaterinburg

 



A. S. Ershova
Ural State Forest Engineering University
Russian Federation

Ershova Anna S. – assistant of department technology of pulp and paper industries and polymer processing

620100. Siberian tract str. 37. Yekaterinburg

 



A. V. Vurasko
Ural State Forest Engineering University
Russian Federation

Vurasko Alesya V. – DSc (Technical), Professor of the department technology of pulp and paper industries and polymer processing 

620100. Siberian tract str. 37. Yekaterinburg

 



V. G. Buryndin
Ural State Forest Engineering University
Russian Federation

Buryndin Victor G. – DSc (Technical), Professor of the department technology of pulp and paper industries and polymer processing

620100. Siberian tract str. 37. Yekaterinburg



References

1. Artemov A.V., Buryndin V.G., Krivonogov P.S. et al. An Investigation of Complexes of Lignin Found in Plant Raw Materials as a Natural Binder in Acquiring Plastic in Closed Molds. Polym. Sci. Ser. D., 2023, no. 16, рр. 278–284.

2. Artemov A.V., Savinovskikh A.V., Buryndin V.G. Modulus of elasticity in bending as an indicator of the physico-mechanical properties of wood plastics without the addition of binders. Systems. Methods. Technologies, 2021, no. 1(49), pp. 67–71. DOI: 10.18324/2077-5415-2021-1-67-71. (In Russ.)

3. Artyomov A.V., Ershova A.S., Savinovskikh A.V. et al. Investigation of biodegradability of wood plastics without the addition of binders based on birch wood. Systems. Methods. Technologies, 2022, no. 3(55), pp. 92–97. DOI: 10.18324/2077-5415-2022-3-92-97. (In Russ.)

4. Barmina I. et al. The Effect of Birch-Bark Addition on the Elemental Composition and Combustion Characteristics of Different Types of Biomass Pellets. Chemical engineering, 2014, vol. 39. pp. 1525–1530.

5. Bazarnova N.G., Galochkin A.I., Krestyanikov V.S. The influence of hydrothermal wood processing on the properties of pressed wood materials. Chemistry of vegetable raw materials, 1997, no. 1, pp. 11–16. (In Russ.)

6. Bazarnova N.G., Galochkin A.I., Krestyanikov V.S. The influence of urea on the properties of pressed materials from wood subjected to hydrothermal treatment. Chemistry of vegetable raw materials, 1997, no. 1, pp. 17–21. (In Russ.)

7. Blondeau D. et al. Antimicrobial activity and chemical composition of white birch (Betula papyrifera Marshall) bark extracts. Microbiologyopen, 2020, vol. 9, no. 1, p. e00944.

8. Buryndin V.G., Artemov A.V., Savinovskikh A.V. et al. Investigation of the production of wood plastics without the addition of binders based on hardwood in the presence of catalysts such as polyoxometallates. Systems. Methods. Technologies, 2020, no. 2(46), pp. 70–75. DOI: 10.18324/2077-5415-2020-2-70-75. (In Russ.)

9. Buryndin V.G., Belchinskaya L.I., Savinovskikh A.V. et al. The study of the production of wood and vegetable plastics without binders in the presence of catalysts such as polyoxometallates. Forestry Journal, 2018, vol. 8, no. 1(29), pp. 128–134. DOI: 10.12737/article_5ab0dfc1e37185.35527284. (In Russ.)

10. Ershova A.S., Artemov A.V., Savinovskikh A.V. et al. The influence of the type of raw materials on the properties of wood plastics without the addition of binders. Systems. Methods. Technologies, 2020, no. 3(47), pp. 74–80. DOI: 10.18324/2077-5415-2020-3-74-80. (In Russ.)

11. Glukhikh V.V., Shkuro A.E., Artyomov A.V. et al. Mathematical planning of experiments and analysis of their results using computer programs: textbook / Ministry of Science and Higher Education of the Russian Federation, Ural State Forestry University. Yekaterinburg: Ural State Forestry University, 2023. 104 p. (In Russ.)

12. Godiņa D. et al. Stability studies of bioactive compounds from birch outer bark ethanolic extracts. Key Engineering Materials, 2018, vol. 762, pp. 152–157.

13. Hordyjewska A. et al. Betulin and betulinic acid: Triterpenoids derivatives with a powerful biological potential. Phytochemistry Reviews, 2019, vol. 18, pp. 929–951. DOI: 10.1007/s11101-019-09623-1

14. Ivanov D.V., Ryabinkov A.A., Orekhov E.V. Aspects of manufacturing fiberboard without the use of synthetic resins. Wood slabs and plywood: theory and practice: materials of the XXIV All-Russian Scientific and Practical Conference, St. Petersburg, March 17–18, 2021. St. Petersburg: Polytech Press, 2021, pp. 79–86. (In Russ.)

15. Jonnalagadda S.C. et al. Recent developments on the synthesis and applications of betulin and betulinic acid derivatives as therapeutic agents. Studies in Natural Products Chemistry, 2017, vol. 53, pp. 45–84. DOI: 10.1016/B978-0-444-63930-1.00002-8

16. Krivorotova A.I., Eskin V.D. Investigation of methods and modes of processing Siberian pine cones in the manufacture of decorative composite material. Coniferous boreal zones, 2022, vol. 40, no. 5, pp. 430–438. DOI: 10.53374/1993-0135-2022-5-430-438. (In Russ.)

17. Kuznetsova S.A., Kuznetsov B.N., Skurydina E.S. et al. Synthesis and properties of biocomposite fertilizers based on urea and birch bark. Journal of the Siberian Federal University. Series: Chemistry, 2013, vol. 6, no. 4, pp. 380–393. (In Russ.)

18. Michurov D.M., Sharkova A.S., Shkuro A.E., Krivonogov P.S. Investigation of wettability and water absorption of composites with polymer polylactide phase and beech sawdust. The woodworking industry, 2023, no. 3, pp. 121–127. (In Russ.)

19. Mikryukova E.V., Sedykh M.A. Lightweight wood slab materials with internal filling from cardboard sleeves. The woodworking industry, 2019, no. 2, pp. 24–30. (In Russ.)

20. Minin A.N. Technology of piezothermoplastics. M.: Forest industry, 1965. 296 p. (In Russ.)

21. Page A. et al. Processing possibilities of birch outer banks into green biocomposites. Environment. Technologies. Resources: Proceedings of the International Scientific and Practical Conference, 2017, vol. 3, pp. 249–253.

22. Paze A. et al. Development of Plywood Binder by Partial Replacement of PhenolFormaldehyde Resins with Birch Outer Bark Components. Key Engineering Materials, 2021, vol. 903, pp. 229–234.

23. Petri V.N. et al. Slab materials and products made of wood and other desalinated residues without the addition of binders. M.: Forest industry, 1976. 360 p.

24. Prosvirnikov D.B., Safin R.R., Kozlov R.R. Assessment of the influence of conditions of catalytic continuous steam-explosive activation of wood on the physical and operational properties of slab wood composite materials based on activated fibers. The woodworking industry, 2020, no. 2, pp. 35–49. (In Russ.)

25. Rizhikovs J. et al. Characterization of suberinic acids from birch outer bark as bio-based adhesive in wood composites. International Journal of Adhesion and Adhesives, 2022, vol. 112, р. 102989. DOI: 10.1016/j.ijadhadh.2021.102989.

26. Safina A.V., Zaripov R.M. The project of production of decorative chips from waste of a woodworking complex. The woodworking industry, 2023, no. 2, pp. 36–45. (In Russ.)

27. Scheffler A. The wound healing properties of betulin from birch bark from bench to bedside. Planta medica, 2019, vol. 85, no. 07, pp. 524–527. DOI: 10.1055/a-0850-0224.

28. Solechnik N.Ya., Natkina L.N., Koromyslova T.S. et al. On the production of wood plastic without binder. Woodworking industry, 1963, no. 3, pp. 15–17. (In Russ.)

29. Sudakova I.G., Garyntseva N.V., Ivanov I.P. et al. Isolation and application of suberin from birch bark bark. Journal of the Siberian Federal University. Series: Chemistry, 2012, vol. 5, no. 2, pp. 168–177. (In Russ.)

30. Valiullina A.I., Grachev A.N., Valeeva A.R. et al. The Use of Biopolyols Obtained from Liquid Birch Sawdust Pyrolysis Products as a Renewable Component in the Production of Rigid Polyurethane Foams. Polymer Science, Series D, 2022, vol. 15, no. 2, рр. 300–305. DOI: 10.1134/S1995421222020307.

31. Vasiliev V.V. Birch bark is a valuable raw material for chemical processing. Wood slabs and plywood: theory and practice: materials of the XXVI All-Russian Scientific and Practical Conference, St. Petersburg, March 21–22, 2023. St. Petersburg: SPbGLTU, 2023, pp. 48–52. (In Russ.)


Review

For citations:


Artyomov A.V., Vlasov N.G., Ershova A.S., Vurasko A.V., Buryndin V.G. nfluence of birch bark content in press raw materials on the properties of birch sawdust-based plastic without resins. Izvestia Sankt-Peterburgskoj lesotehniceskoj akademii. 2024;(250):333-352. (In Russ.) https://doi.org/10.21266/2079-4304.2024.250.333-352

Views: 54


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2079-4304 (Print)
ISSN 2658-5871 (Online)