Polyamidoamine-epichlorohydrin resins based on disproportionated tall oil rosin
https://doi.org/10.21266/2079-4304.2025.253.282-292
Abstract
In order to expand the areas of application of disproportionated tall oil rosin with a low color value on the Gardner scale and to obtain the sizing compositions (cationic sizes) for paper and cardboard, the polyamidoamine and polyamidoamineepichlorohydrin resins have been synthesized. The synthesis of polyamidoamine resin based on disproportionated tall oil rosin, adipic acid, diethylenetriamine, and 2- aminoethanol was carried out in vacuum at 140–150 °C for 7 hours, the addition of epichlorohydrin to polyamidoamine and the preparation of polyamidoamineepichlorohydrin resin – at 40–60°C for 1 hour. It was found that 20% solutions of polyamidoamine and polyamidoamine-epichlorohydrin resins are stable when stored for 30 days at 20–24 °C, the dynamic viscosity at 25 °C was 105 and 114 mPa·s, respectively. The color of 50% solutions deteriorated slightly compared to the original disproportionated tall oil rosin not more 3 on the Gardner scale.
About the Authors
A. V. Kurzin
Saint Petersburg State University of Industrial Technologies and Design
Russian Federation
Russian Federation
KURZIN Aleksandr V. – PhD (Chemical), Assistant Professor of the Organic Chemistry Department, Higher School of Technology and Energetics
198095. 1 Ivana Chernykh str. 4. St. Petersburg
SCOPUS AuthorID: 6602875595
K. A. Piskounov
Amber Stream LLC; JSC Ilim Group
Russian Federation
Russian Federation
PISKOUNOV Kirill A. – CEO; Excellence and Development Director, Forest Chemicals
165650. Dybtsyna str. 42. Koryazhma. Arkhangelsk Region
191025. Marata str. 17. St. Petersburg
A. A. Tarazanov
Saint Petersburg State University of Industrial Technologies and Design
Russian Federation
Russian Federation
TARAZANOV Aleksey A. – Senior Lecturer of the Technology of Cellulose and Composite Materials Department, Higher School of Technology and Energetics
198095. Ivana Chernykh str. 4. St. Petersburg
SCOPUS AuthorID: 57885562200
A. N. Evdokimov
Saint Petersburg State University of Industrial Technologies and Design
Russian Federation
Russian Federation
EVDOKIMOV Andrey N. – PhD (Chemical), Head of the Department of Materials Science and Engineering Technology, Higher School of Technology and Energetics, Assistant Professor
198095. Ivana Chernykh str. 4. St. Petersburg
SCOPUS AuthorID: 7006217216
WoS ResearcherID: G-5637-2016
A. Yu. Korochinskiy
Saint Petersburg State University of Industrial Technologies and Design
Russian Federation
Russian Federation
KOROCHINSKIY Aleksandr Yu. – Student, Organic Chemistry Department, Higher School of Technology and Energetics
198095. Ivana Chernykh str. 4. St. Petersburg
References
1. Chernaya N.V., German N.A. Synthetic materials in paper and cardboard production: resource conservation and import substitution. Minsk: BGTU, 2020. 205 p. (In Russ.)
2. Evstigneyev E.I., Grinenko E.V., Vasiliev A.V. Obtaining hydrogels of technical lignins. Izvestia Sankt-Peterburgskoj Lesotehniceskoj Akademii, 2021, iss. 235, pp. 270–291. (In Russ.). DOI: 10.21266/20794304.2021.235.274-295.
3. Fleisher V.L., Chernaya N.V., Makarova D.S., Gordeiko S.A., Germas’ A.V. Synthesis of new polymers based on rosin acid amides for strengthening waste paper. Trudy BSTU. Ser. 4: Khimiya, Tekhnologiya Organicheskikh Veschestv, Biotekhnologiya, 2014, no. 4 (168), pp. 134–136. (In Russ.)
4. Fleisher V.L., Chernaya N.V. Modified rosin: production, properties, application. Minsk: BGTU, 2019. 304 p. (In Russ.)
5. Golovin A.I., Trofimov A.N., Uzlov G.A., Zhukova I.P., Kiprianov A.I., Prokhorchuk T.I., Kovalev V.E. Wood chemical byproducts of the sulfate pulping production. Moscow: Lesn. prom-st', 1988. 288 р. (In Russ.)
6. Gordeiko S.A., Chernaya N.V., Zholnerovich N.V., Fleisher V.L., Makarova D.S. Specificities of the application of polycondensation products of adipic acid with diethylenetriamine and rosin acids in the paper technology. Trudy BSTU. Ser. 4: Khimiya, Tekhnologiya Organicheskikh Veschestv, Biotekhnologiya, 2014, no. 4 (168), pp. 130–133. (In Russ.)
7. Gordeiko S.A., Chernaya N.V., Shishakov E.P. Reinforcement of scrap paper and recycled cardboard sized in acidic, neutral and weakly alkaline media. IVUZ. Lesnoy Zhurnal, 2015, no. 5, pp. 165–173. DOI: 10.17238/issn0536-1036.2015.5.165. (In Russ.)
8. Hiscock K., Krajca K. Rosin ester handbook. Almere: Arizona Chemical – International Paper, 2007. 175 р.
9. Kurzin A.V., Evdokimov A.N. Pour point depressants for fuels based on tall oil fatty acid esters. Izvestia Sankt-Peterburgskoj Lesotehniceskoj Akademii, 2021, iss. 237, pp. 196–203. (In Russ.). DOI: 10.21266/20794304.2021.237.196-203.
10. Luo Y., Grigoriev V., Lu C., Rosencrance S. Paper and methods for production of paper. Patent RU 2581862. 2016. (In Russ.)
11. Marten M., Kamutzki W. Aqueous solutions of polyamidoamine-epichlorohydrin resins, and preparation and use thereof. Patent US 5019606. 1991.
12. Papkov V.N., Rivin E.M., Blinov E.V. Styrene-butadiene rubbers. Synthesis and properties. Voronezh: VGUIT, 2015. 313 p. (In Russ.)
13. Varankina G.S., Rusakov V.S. Modification of phenol-formaldehyde resin by byproducts of sulfate pulp production. Izvestia Sankt-Peterburgskoj Lesotehniceskoj Akademii, 2013, iss. 204, pp. 130–137. (In Russ.)
14. Zagidullin R.N., Rasulev Z.G., Abdrafikova L.S., Guryanov V.E., Sarana N.V., Skachkov A.S. Method for preparation of amidoepichlorohydrin resin. Patent RU 2065454. 1996. (In Russ.)
15. Zhuravlev P.I. Rosin, turpentine, and their processing products. Moscow: Lesn. prom-st', 1988. 71 р. (In Russ.).
Review
For citations:
Kurzin A.V., Piskounov K.A., Tarazanov A.A., Evdokimov A.N., Korochinskiy A.Yu. Polyamidoamine-epichlorohydrin resins based on disproportionated tall oil rosin. Izvestia Sankt-Peterburgskoj lesotehniceskoj akademii. 2025;(253):282-292. (In Russ.) https://doi.org/10.21266/2079-4304.2025.253.282-292
Views:
12
Email this article 